Now showing 1 - 10 of 112
  • Publication
    Open Access
    Generalized brewster angle effect in thin-film optical absorbers and its application for graphene hydrogen sensing
    (American Chemical Society, 2019)
    Sreekanth, Kandammathe Valiyaveedu
    ;
    Mohamed ElKabbash
    ;
    Medwal, Rohit
    ;
    Zhang, Jihua
    ;
    Letsou, Theodore
    ;
    Strangi, Giuseppe
    ;
    Hinczewski, Michael
    ;
    ;
    Guo, Chunlei
    ;
    Ranjan Singh
    Generalized Brewster angle (GBA) is the incidence angle at polarization by reflection for p- or s-polarized light takes place. Realizing s-polarization Brewster effect requires a material with magnetic response which is challenging at optical frequencies since the magnetic response of materials at these frequencies is extremely weak. Here, we experimentally realize GBA effect in the visible using a thin-film absorber system consisting of a dielectric film on an absorbing substrate. Polarization by reflection is realized for both p- and s- polarized light at different angles of incidence and multiple wavelengths. We provide a theoretical framework for the generalized Brewster effect in thin-film light absorbers. We demonstrate hydrogen gas sensing using a single layer graphene film transferred on a thin-film absorber at the GBA with ~1 fg/mm2 aerial mass sensitivity. The ultrahigh sensitivity stems from the strong phase sensitivity near point-of-darkness, particularly at the GBA, and the strong light-matter interaction in planar nanocavities. These findings depart from the traditional domain of thin-films as mere interference optical coatings and highlight its many potential applications including gas sensing and biosensing.
    WOS© Citations 37Scopus© Citations 47  298  200
  • Publication
    Open Access
    Computing plasma focus pinch current from total current measurement
    (American Institute of Physics, 2008)
    Lee, Sing
    ;
    Saw, Sor Heoh
    ;
    ; ;
    Schmidt, H.

    The total current Itotal waveform in a plasma focus discharge is the most commonly measured quantity, contrasting with the difficult measurement of Ipinch. However, yield laws should be scaled to focus pinch current Ipinch rather than the peak Itotal. This paper describes how Ipinch may be computed from the Itotal trace by fitting a computed current trace to the measured current trace using the Lee model. The method is applied to an experiment in which both the Itotal trace and the plasma sheath current trace were measured. The result shows good agreement between the values of computed and measured Ipinch.

    WOS© Citations 52Scopus© Citations 63  234  347
  • Publication
    Metadata only
    Substrate orientation dependent characteristics of half-metallic and metallic superlattices [La0. 7Sr0. 3MnO3/LaNiO3] 10
    (American Institute of Physics, 2022)
    Das, Shaona
    ;
    Tanguturi, Ranganadha Gopalarao
    ;
    Ghosh, Sayandeep
    ;
    Dokala, Ravi Kiran
    ;
    Medwal, Rohit
    ;
    Gupta, Surbhi
    ;
    Yan, Zhuo
    ;
    Qi, Yan
    ;
    ;
    Thota, Subhash
    We report a detailed study on the orientation dependent growth characteristics, electronic structure, transport, magnetic, and vibrational excitations in atomically flat interfaces of [La0.7Sr0.3MnO3/LaNiO3]10 superlattices (SLs) coherently grown on (001/011/111)-SrTiO3 substrates by the pulsed laser deposition technique. X-ray reflectometry confirms the periodic superlattice stacks from the Kiessig interference fringes and well-defined even interfaces between the nickelate and manganite layers. A complex local atomic environment across the interfaces was noticed, yet trivalent La, divalent Sr, and mixed valent Ni2+/3+ and Mn3+/4+ electronic states prevail at the core level with enhanced relative intensity ratio of the Mn ions in the superlattices grown on (111) oriented SrTiO3 substrates as compared to those grown on (001) and (011) oriented SrTiO3. The temperature (5≤T≤300K) dependence of electrical resistivity 𝜌(𝑇) analysis reveals 3D variable range hopping model [𝜌(T)=𝜌0exp(T0/T)(1/4)] with large magnitude of hopping energies (≥40 meV) for the SL-111 system associated with the high energy gap developed by the accumulation of disorderness in the individual constituents of polar layers. Moreover, all SL systems exhibit reduced ferromagnetic ordering temperatures (67≤T𝐶≤110K) with a low-temperature anomaly (11.4≤T∗≤22K) and a substantial enhancement in the effective exchange interaction (J𝑒𝑓𝑓∼3.52meV) having altered ground state-spin configuration S∼1/2 different from S=3/2 of La0.75Sr0.25MnO3. Nevertheless, the SL-011 system exhibits large anisotropy field H𝐾∼18kOe and cubic anisotropy constant K1∼9.3×103J/m3 in comparison to the other two orientations. The second order two-phonon interaction driven by the local polaronic distortion causes significant changes in the vibrational excitations of the investigated system. Nonetheless, most of the Raman modes follow the substrate-induced, highly oriented epitaxial growth pattern except for two modes 𝜈4 (326cm−1) and 𝜈8 (728cm−1), which slightly differ in the case of SL-111 superlattices.
    WOS© Citations 2Scopus© Citations 2  121
  • Publication
    Open Access
    Current sheath formation in the plasma focus
    (World Scientific, 2014)
    Seng, Yeow Sing
    ;
    ;
    The shaping and formation of the current sheath takes place in the breakdown phase of a plasma focus device. Achieving a clear understanding of the current sheath formation process is important because the plasma focus device performance depends on the quality of this sheath. In this paper, we created and successfully run an electromagnetic particle in cell code to simulate the breakdown phase. Magnetic effects are self-consistently incorporated in this formalism, allowing us to carry the simulation all the way to the point prior to breakdown.
      223  203
  • Publication
    Open Access
    Anisotropy-assisted bias-free spin Hall nano-oscillator
    (American Institute of Physics, 2023)
    Manna, Sourabh
    ;
    Medwal, Rohit
    ;
    Gupta, Surbhi
    ;
    Mohan, John Rex
    ;
    Fukuma, Yasuhiro
    ;
    Ferromagnet/nonmagnet (FM/NM) bilayer-based spin Hall nano-oscillators (SHNOs)—a sub-class of spintronic oscillator devices—have promising potential toward realizing low-power physical reservoir computing systems because of their inherent nonlinearity and miniature form factor. However, most of the studies on SHNOs indicate that an external biasing magnetic field is necessary for their operation, creating a bottleneck for their practical implementation in designing small and compact RC hardware. In this report, using micromagnetic simulation, we demonstrate biasing field-free operation of a FM/NM bilayer-based SHNO by exploiting the magnetic anisotropy. Our results reveal that the magnetic anisotropy in the FM layer provides active control over the DC tunability of auto-oscillation frequency and the threshold value of current needed for sustained auto-oscillations. We show that the increase in uniaxial anisotropy substantially modifies the spatial profile of auto-oscillation and eventually leads to the reduction in the threshold current for auto-oscillation, which could be utilized to design low-power computing hardware using SHNO devices.
    WOS© Citations 4Scopus© Citations 8  92  58
  • Publication
    Open Access
    Backward high energy ion beams from plasma focus
    (American Institute of Physics, 2009)
    Roshan, M. V.
    ;
    ;
    Lee, Sing
    ;
    Talebitaher, A.
    ;
    ;

    High energy neutrons, more than 2.45 MeV from deuteron-deuteron fusion reaction, have been measured in backward direction of plasma focus devices in many laboratories. However the experimental evidence for high energy deuterons responsible for such neutrons has not been reported so far. In this brief communication, backward high energy deuteron beam from NX2 plasma focus [M. V. Roshan et al., Phys. Lett. A 373, 851 (2009)] is reported, which was measured with a direct and unambiguous technique of nuclear activation. The relevant nuclear reaction for the target activation is 12C (d, n)13N , which has a deuteron threshold energy of 328 keV.

    WOS© Citations 14Scopus© Citations 16  402  198
  • Publication
    Open Access
    Mechanically robust anti-fingerprint coating on polycarbonate substrate
    (Elsevier, 2022)
    Sun, Ye
    ;
    ;
    Chen, Zhong
    Mechanical robustness is required for a wide range of protective coatings for their long-term usage. It is particularly crucial for the coatings on polymeric substrates to maintain the surface free of contamination such as dust and fingerprint. Here, we have developed an effective fabrication method to prepare amphiphobic anti-fingerprint coating on polycarbonate (PC) substrates. Thin films with porous silicon dioxide (SiO2) nanoparticles were deposited via pulse laser deposition on plasma pre-treated PC substrate. After the coating is applied, trichloro(1H,1H,2H,2H-perfluorooctyl) silane (PFTS) was assembled on the silica surface. The as-prepared PFTS-treated silica coating is superhydrophobic with water contact angle at 155.2 ± 1.8° and highly oleophobic with a contact angle of 133.6 ± 3.3° with diiodomethane. The coating also displays excellent adhesion with the PC substrate. The developed room temperature deposition process makes it potentially applicable for other low melting point polymeric substrates towards a wider range of functional surface applications.
    WOS© Citations 10Scopus© Citations 12  74  22
  • Publication
    Open Access
    Investigating the role of precipitating agents on the electrochemical performance of MgCo2O4
    (Elsevier, 2019)
    Kulkarni Pranav
    ;
    Chepurthy Varnika
    ;
    Low, Beverly Ying Tong
    ;
    Debasis Ghosh
    ;
    Geetha Balakrishna
    ;
    ;
    Adams, S.
    ;
    Reddy, M. V.
    In this article, we investigated the role of K and Li hydroxide (KOH & LiOH) as precipitating agents on the physiochemical properties and electrochemical performance of MgCo2O4. Uniform cubic particles were obtained using lithium hydroxide. When LiOH was used as precipitating agents, discrete nanoparticles with uniform particle size were obtained. Whereas KOH as precipitating agent resulted in more agglomerated particles with non-uniform size distribution. After testing, we found that MgCo2O4 nanostructures prepared with LiOH showed high initial discharge/charge capacity of 1384/1013 mA h g-1 at current density of 60 mA g-1, and retained a high reversible capacity of 899 mA h g-1 over 50 cycles, which was superior in comparison to the electrochemical performance of the MgCo2O4 prepared using KOH as precipitating agent. The high electrochemical performance can be attributed to the small particle size and crystallinity of MgCo2O4 obtained using LiOH.
    WOS© Citations 6Scopus© Citations 9  264  131
  • Publication
    Open Access
    Highly dose dependent damping-like spin‒orbit torque efficiency in O-implanted Pt
    (American Institute of Physics, 2021)
    Shashank, Utkarsh
    ;
    Medwal, Rohit
    ;
    Nakamura, Yoji
    ;
    Mohan, John Rex
    ;
    Nongjai, Razia
    ;
    Kandasami, Asokan
    ;
    ;
    Asada, Hironori
    ;
    Gupta, Surbhi
    ;
    Fukuma, Yasuhiro

    Damping-like torque (DLT) arising from the spin Hall effect (SHE) in heavy metals and their alloys has been widely explored for applications in spin–orbit torque MRAM, auto-oscillations, spin waves, and domain wall motion. In conventional materials, the DLT efficiency is limited by intrinsic properties, while attaining strong spin–orbit coupling and higher spin-charge interconversion, with no compromise to electric properties, is the need of the hour. In this Letter, we report more than 3.5 times increase in DLT efficiency, θDL, of modified Pt-oxide by employing a better approach of low energy 20 keV O+ ion implantation. The highest fluence of O+ implantation (1 × 1017 ions cm−2) in Pt enhanced the DLT efficiency from 0.064 to 0.230 and improved the spin transmission for a smaller trade-off in the longitudinal resistivity (𝜌Pt to 𝜌Pt−Oxide) from 55.4 to 159.5 μΩ cm, respectively. The transverse spin Hall resistivity, 𝜌SH, is found to be proportional to the square of the longitudinal resistivity, i.e., 𝜌impSH∝𝜌2imp, implying that the enhanced SHE in O-implanted Pt is due to a side-jumping mechanism. Further, no break in the twofold as well as mirror symmetry of torques from the O-implanted Pt allows the use of spin-torque ferromagnetic resonance-based line shape analysis to quantify such torques.

    WOS© Citations 13Scopus© Citations 18  362  249
  • Publication
    Open Access
    Nanostructured polycrystalline Ni3S2 as electrode material for lithium ion batteries
    (IOP Publishing, 2020)
    Khan, I. A.
    ;
    Medwal, Rohit
    ;
    Fareed, S.
    ;
    Farid, A.
    ;
    Vas, Joseph Vimal
    ;
    Reddy, M. V.
    ;
    We report the facile synthesis of nanostructured polycrystalline nickel sulphide (NP-Ni3S2) on Ni foil at 750 and 800 °C by employing powder vapor transport technique. X-ray diffraction patterns(XRD) confirms the formation of polycrystalline Ni3S2 phase with rhombohedral structure. Raman spectroscopy and x-ray photo-electron spectroscopy (XPS)further confirms the formation of Ni3S2 phase. Scanning electron microscopy (SEM)reveals the formation of flower shaped nanostructures of NP-Ni3S2 material. As an electrode material of Li+ batteries, the initial discharge capacities for NP-Ni3S2 materials deposited at 750 and 800 °C are found to be∼2649 mAh g−1 and∼1347 mAh g−1, respectively with initial capacity loss of∼1067 mAh g−1 and∼363 mAh g−1 after first cycle and capacities of∼931 mAh g−1 and∼818 mAh g−1 after 30 cycles for a current density of 60 mA g−1. An excellent capacity retention for NP-Ni3S2 material synthesized at 800 °C is due to its larger surface area and shorter diffusion length for mass and charge transport brought about by the flower-like porous nanostructures showing that the NP-Ni3S2 material synthesized at higher temperatures is more suitable as electrode material for Li+ batteries.
    WOS© Citations 11Scopus© Citations 16  312  129